Respuesta :
Answer : The value of change in entropy for freezing process is, -18.07 J/mol.K
Explanation :
Formula used :
[tex]\Delta S=\frac{\Delta H_{freezing}}{T_f}[/tex]
where,
[tex]\Delta S[/tex] = change in entropy
[tex]\Delta H_{fus}[/tex] = change in enthalpy of fusion = 3.17 kJ/mol
As we know that:
[tex]\Delta H_{fus}=-\Delta H_{freezing}=-3.17kJ/mol=-3170J/mol[/tex]
[tex]T_f[/tex] = freezing point temperature = [tex]-97.6^oC=273+(-97.6)=175.4K[/tex]
Now put all the given values in the above formula, we get:
[tex]\Delta S=\frac{\Delta H_{freezing}}{T_m}[/tex]
[tex]\Delta S=\frac{-3170J/mol}{175.4K}[/tex]
[tex]\Delta S=-18.07J/mol.K[/tex]
Therefore, the value of change in entropy for freezing process is, -18.07 J/mol.K
Answer:
Entropy is defined as the measure of possible arrangement of the atoms or molecules. Entropy change for the the freezing process mole of 1 liquid methanol at -97.6 degree celcius and 1 atm will be -18.07 J/mol.K
Explanation:
The entropy change can be calculated by the given formula:
[tex]\begin{aligned} \Delta \text S &= \frac{\Delta \text H_{\text {freezing}}}{\text T_{f}} \end{aligned}[/tex]
in which,
[tex]\Delta \text S[/tex] = change in entropy
[tex]\Delta \text H_{\text {fusion}} &=[/tex] change in enthalpy of fusion that is -3.17 kJ/mol (as given).
By the formula of enthalpy change,
[tex]\begin{aligned} \Delta \text H_{\text {fusion}} &= - \Delta \text H_{\text {freezing}} &= -3.17 {\text {kJ/mol}} &= -3170 \text {J/mol}\end{aligned}[/tex]
Now,
[tex]{\text T_{f}}[/tex] = Freezing Point Temperature = [tex]-97.6^{o} \text C[/tex] = 273 + (-97.6) = -175.4 K
Substituting the values in above equation of entropy change, we get,
[tex]\begin{aligned} \Delta \text S &= \frac{\Delta \text H_{\text {freezing}}}{\text T_{f}} \end{aligned}[/tex]
[tex]\begin{aligned} \Delta \text S &= \frac{-3170 \text {J/mol}}{175.4 \text {K}} \\\\Delta \text S& = -18.07 \text {J/mol.K}\end{aligned}[/tex]
Thus, the value of change in entropy for freezing process of 1 mole of liquid methanol is -18.07 J/mol.k
For Further Reference:
https://brainly.com/question/14591611?referrer=searchResults